Treatments of Lignocellulosic Hydrolysates and Continuous-Flow Hydrogenation of Xylose to Xylitol

Anikó Fehér, Csaba Fehér, Margaréta Rozbach, Gergely Rácz, Melinda Fekete, L. Hegedûs, Zsolt Barta

Research output: Article

Abstract

Xylitol is produced by the heterogeneous catalytic hydrogenation of xylose over Raney nickel. The hydrogenation must typically be followed by several purification steps, which makes the chemical production relatively complex and expensive. In this study, activated carbon and bio-purification treatments of corn stover hydrolysates and subsequent nickel-catalyzed hydrogenation of xylose to xylitol were investigated. The activated carbon treatment was used to eliminate inhibitory compounds and increase the efficiency of the bio-purification step. It was found that the glucose could be completely eliminated from the hydrolysate. The hydrogenation reactions of corn stover hydrolysate demonstrated that a high reaction temperature resulted in high sugar alcohol yields and selectivity. At a given temperature, the flow rate had no significant effect on xylitol yield.

Original languageEnglish
Pages (from-to)496-503
Number of pages8
JournalChemical Engineering and Technology
Volume41
Issue number3
DOIs
Publication statusPublished - márc. 1 2018

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Xylitol
Xylose
Hydrogenation
Purification
Nickel
Activated carbon treatment
Sugar Alcohols
Activated carbon
Glucose
Flow rate
Temperature

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Industrial and Manufacturing Engineering

Cite this

Treatments of Lignocellulosic Hydrolysates and Continuous-Flow Hydrogenation of Xylose to Xylitol. / Fehér, Anikó; Fehér, Csaba; Rozbach, Margaréta; Rácz, Gergely; Fekete, Melinda; Hegedûs, L.; Barta, Zsolt.

In: Chemical Engineering and Technology, Vol. 41, No. 3, 01.03.2018, p. 496-503.

Research output: Article

Fehér, Anikó ; Fehér, Csaba ; Rozbach, Margaréta ; Rácz, Gergely ; Fekete, Melinda ; Hegedûs, L. ; Barta, Zsolt. / Treatments of Lignocellulosic Hydrolysates and Continuous-Flow Hydrogenation of Xylose to Xylitol. In: Chemical Engineering and Technology. 2018 ; Vol. 41, No. 3. pp. 496-503.
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AU - Hegedûs, L.

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