The Molecular Structure of Pentafluorobenzene Sulphonyl Chloride

Erzsébet Vajda, István Hargittai

Research output: Article

4 Citations (Scopus)

Abstract

The molecular geometry of pentafluorobenzene sulphonyl chloride is characterized by the following bond lengths (rg) and bond angles from an electron diffraction study: C–F 132.6 ± 0.3 pm, C–C 139.1 ± 0.7 pm, S=O 141.5 ± 0.3 pm, S–Cl 202.7 ± 0.5 pm, C–S 179.8 ± 0.6 pm, C–S-Cl 104.8 ± 0.8°, C–S=O 108.2 + 0.6°, O=S=0 123.6 ± 1.0°, C1±S=O 105.3 ±0.2°. The molecular model is asymmetric; the benzene ring is rotated by 61.8 ± 2.2° relative to the plane containing the S–l bond and bisecting the O = S = O angle. The benzene ring is not distorted considerably.

Original languageEnglish
Pages (from-to)765-768
Number of pages4
JournalZeitschrift fur Naturforschung - Section A Journal of Physical Sciences
Volume38
Issue number7
DOIs
Publication statusPublished - júl. 1 1983

ASJC Scopus subject areas

  • Mathematical Physics
  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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