Stereochemistry of the hydrogenolysis of oxacycloalkanes on metal catalysts

Research output: Article

12 Citations (Scopus)

Abstract

On the basis of reaction kinetics, H-D exchange, and i.r. studies of the hydrogenolysis of oxirans and oxolans, the opposite regio- and stereo-selectivities of Pt and Ni are interpreted, a new reaction mechanism is proposed, and it is shown experimentally that the reaction mechanism depends inter alia on the steric structure of the molecule.

Original languageEnglish
Pages (from-to)667-668
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number14
Publication statusPublished - 1980

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Stereoselectivity
Hydrogenolysis
Stereochemistry
Reaction kinetics
Ion exchange
Metals
Catalysts
Molecules

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

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title = "Stereochemistry of the hydrogenolysis of oxacycloalkanes on metal catalysts",
abstract = "On the basis of reaction kinetics, H-D exchange, and i.r. studies of the hydrogenolysis of oxirans and oxolans, the opposite regio- and stereo-selectivities of Pt and Ni are interpreted, a new reaction mechanism is proposed, and it is shown experimentally that the reaction mechanism depends inter alia on the steric structure of the molecule.",
author = "M. Bart{\'o}k and F. Notheisz",
year = "1980",
language = "English",
pages = "667--668",
journal = "Chemical Communications",
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publisher = "Royal Society of Chemistry",
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AU - Bartók, M.

AU - Notheisz, F.

PY - 1980

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AB - On the basis of reaction kinetics, H-D exchange, and i.r. studies of the hydrogenolysis of oxirans and oxolans, the opposite regio- and stereo-selectivities of Pt and Ni are interpreted, a new reaction mechanism is proposed, and it is shown experimentally that the reaction mechanism depends inter alia on the steric structure of the molecule.

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