Rate constant for the reaction of OH radicals with CH3 C(O)Cl determined by direct kinetic method

Rebeka Nádasdi, István Szilágyi, Gergely Kovács, Sándor Dóbé, Tibor Bérces, Ferenc Márta

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1 Citation (Scopus)

Abstract

The fast flow technique with OH resonance fluorescence detection has been applied at T = 298 ± 2 K to study the kinetics of the overall reaction: H + CH3C(O)Cl → products (1) A rate constant value of k 1 = (1.02 ± 0.12) x 1010 cm3 mol -1 s-1 has been determined which is the first direct kinetic parameter reported for reaction (1) in the literature (the error given refers to 2σ accuracy).

Original languageEnglish
Pages (from-to)193-199
Number of pages7
JournalReaction Kinetics and Catalysis Letters
Volume89
Issue number1
DOIs
Publication statusPublished - okt. 1 2006

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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