Positron annihilation and 1H NMR study of [Zn(1-propyltetrazole)6] (BF4)2 and [Fe(methyltetrazole)6] (BF4)2 complexes

M. Bokor, T. Marek, K. Süvegh, K. Tompa, A. Vértes, Zs Nemes-Vetéssy, K. Burger

Research output: Article

6 Citations (Scopus)

Abstract

The complexes [Zn(1-propyltetrazole)6](BF4)2 (Zn-ptz) and [Fe(methyltetrazole)6](BF4)2 (Fe-mtz) were investigated by position annihilation and solid-state NMR spectroscopy. For Zn-ptz signs of structural rearrangements were found between 70 and 145 K. For the spin-crossover complex Fe-mtz a transition affecting the high-spin state Fe2+ ions at lattice site B occurs below 15 K.

Original languageEnglish
Pages (from-to)247-253
Number of pages7
JournalJournal of Radioanalytical and Nuclear Chemistry
Volume211
Issue number1
DOIs
Publication statusPublished - jan. 1 1996

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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