Plane stress fracture toughness of physically aged plasticized PETG as assessed by the essential work of fracture (EWF) method

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Abstract

The plane stress fracture toughness of amorphous copolyester (PETG) sheets plasticized by various amount of neopentylglycol dibenzoate (NPGDB in 0, 5, 10 and 20 wt%) was studied in as-received (AR) and rejuvenated (RJ) states by adopting the essential work of fracture (EWF) method. EWF tests were performed on deeply double-edge notched tensile loaded (DDEN-T) specimens at various deformation rates (2,10 and 100 mm/min) at room temperature. It was established that physical aging strongly affected the EWF terms. The specific yielding-related EWF increased with increasing deformation rate and decreased with increasing plasticizer content. The specific non-essential work and its necking-related constituent, which changed parallel to each other, remained constant up to 10 wt% NPGDB content and decreased afterwards. The plastic zone in the DDEN-T specimens was formed by cold drawing which is governed by the entanglement structure. This This was demonstrated by the shape recovery of the plastic zone in the broken DDEN-T specimens after heating them above the T g of the related PETG compound.

Original languageEnglish
Pages (from-to)5691-5699
Number of pages9
JournalPolymer (United Kingdom)
Volume44
Issue number19
DOIs
Publication statusPublished - aug. 21 2003

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Fracture toughness
Plastics
Plasticizers
Aging of materials
Heating
Recovery
phenylethylthio-beta-galactopyranoside
Temperature

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics

Cite this

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title = "Plane stress fracture toughness of physically aged plasticized PETG as assessed by the essential work of fracture (EWF) method",
abstract = "The plane stress fracture toughness of amorphous copolyester (PETG) sheets plasticized by various amount of neopentylglycol dibenzoate (NPGDB in 0, 5, 10 and 20 wt{\%}) was studied in as-received (AR) and rejuvenated (RJ) states by adopting the essential work of fracture (EWF) method. EWF tests were performed on deeply double-edge notched tensile loaded (DDEN-T) specimens at various deformation rates (2,10 and 100 mm/min) at room temperature. It was established that physical aging strongly affected the EWF terms. The specific yielding-related EWF increased with increasing deformation rate and decreased with increasing plasticizer content. The specific non-essential work and its necking-related constituent, which changed parallel to each other, remained constant up to 10 wt{\%} NPGDB content and decreased afterwards. The plastic zone in the DDEN-T specimens was formed by cold drawing which is governed by the entanglement structure. This This was demonstrated by the shape recovery of the plastic zone in the broken DDEN-T specimens after heating them above the T g of the related PETG compound.",
keywords = "Amorphous copolyester, Essential work of fracture (EWF), Plasticizer",
author = "J. Karger-Kocsis and T. B{\'a}r{\'a}ny and Moskala, {E. J.}",
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T1 - Plane stress fracture toughness of physically aged plasticized PETG as assessed by the essential work of fracture (EWF) method

AU - Karger-Kocsis, J.

AU - Bárány, T.

AU - Moskala, E. J.

PY - 2003/8/21

Y1 - 2003/8/21

N2 - The plane stress fracture toughness of amorphous copolyester (PETG) sheets plasticized by various amount of neopentylglycol dibenzoate (NPGDB in 0, 5, 10 and 20 wt%) was studied in as-received (AR) and rejuvenated (RJ) states by adopting the essential work of fracture (EWF) method. EWF tests were performed on deeply double-edge notched tensile loaded (DDEN-T) specimens at various deformation rates (2,10 and 100 mm/min) at room temperature. It was established that physical aging strongly affected the EWF terms. The specific yielding-related EWF increased with increasing deformation rate and decreased with increasing plasticizer content. The specific non-essential work and its necking-related constituent, which changed parallel to each other, remained constant up to 10 wt% NPGDB content and decreased afterwards. The plastic zone in the DDEN-T specimens was formed by cold drawing which is governed by the entanglement structure. This This was demonstrated by the shape recovery of the plastic zone in the broken DDEN-T specimens after heating them above the T g of the related PETG compound.

AB - The plane stress fracture toughness of amorphous copolyester (PETG) sheets plasticized by various amount of neopentylglycol dibenzoate (NPGDB in 0, 5, 10 and 20 wt%) was studied in as-received (AR) and rejuvenated (RJ) states by adopting the essential work of fracture (EWF) method. EWF tests were performed on deeply double-edge notched tensile loaded (DDEN-T) specimens at various deformation rates (2,10 and 100 mm/min) at room temperature. It was established that physical aging strongly affected the EWF terms. The specific yielding-related EWF increased with increasing deformation rate and decreased with increasing plasticizer content. The specific non-essential work and its necking-related constituent, which changed parallel to each other, remained constant up to 10 wt% NPGDB content and decreased afterwards. The plastic zone in the DDEN-T specimens was formed by cold drawing which is governed by the entanglement structure. This This was demonstrated by the shape recovery of the plastic zone in the broken DDEN-T specimens after heating them above the T g of the related PETG compound.

KW - Amorphous copolyester

KW - Essential work of fracture (EWF)

KW - Plasticizer

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