Phosphinerhodium complexes as homogeneous catalysts. XI. Decarbonylation of primary alcohols used as solvents under conditions of olefin hydrogenation; a side reaction leading to catalyst deactivation

L. Kollár, Szilárd Toros, Bálint Heil, László Markó

Research output: Article

15 Citations (Scopus)

Abstract

In the hydrogenation of olefins in alcoholic solvents catalysed by phosphinerhodium complexes a hydrogen transfer reaction from the alcohols to the olefins takes place alongside the main reaction. With primary alcohols the aldehydes formed are decarbonylated and the in situ catalysts formed from [Rh(diene)Cl]2 and phosphines are partially converted into Rh(CO)(PR3)2Cl type complexes and thereby deactivated.

Original languageEnglish
Pages (from-to)253-256
Number of pages4
JournalJournal of Organometallic Chemistry
Volume192
Issue number2
DOIs
Publication statusPublished - jún. 17 1980

Fingerprint

Catalyst deactivation
Hydrogenation
Alkenes
deactivation
alkenes
Olefins
hydrogenation
alcohols
Alcohols
Phosphines
catalysts
Catalysts
dienes
Carbon Monoxide
Aldehydes
aldehydes
phosphines
Hydrogen
hydrogen

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

@article{8e3fd112cbe14b5d898bd2647e2b2566,
title = "Phosphinerhodium complexes as homogeneous catalysts. XI. Decarbonylation of primary alcohols used as solvents under conditions of olefin hydrogenation; a side reaction leading to catalyst deactivation",
abstract = "In the hydrogenation of olefins in alcoholic solvents catalysed by phosphinerhodium complexes a hydrogen transfer reaction from the alcohols to the olefins takes place alongside the main reaction. With primary alcohols the aldehydes formed are decarbonylated and the in situ catalysts formed from [Rh(diene)Cl]2 and phosphines are partially converted into Rh(CO)(PR3)2Cl type complexes and thereby deactivated.",
author = "L. Koll{\'a}r and Szil{\'a}rd Toros and B{\'a}lint Heil and L{\'a}szl{\'o} Mark{\'o}",
year = "1980",
month = "6",
day = "17",
doi = "10.1016/S0022-328X(00)94429-2",
language = "English",
volume = "192",
pages = "253--256",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "2",

}

TY - JOUR

T1 - Phosphinerhodium complexes as homogeneous catalysts. XI. Decarbonylation of primary alcohols used as solvents under conditions of olefin hydrogenation; a side reaction leading to catalyst deactivation

AU - Kollár, L.

AU - Toros, Szilárd

AU - Heil, Bálint

AU - Markó, László

PY - 1980/6/17

Y1 - 1980/6/17

N2 - In the hydrogenation of olefins in alcoholic solvents catalysed by phosphinerhodium complexes a hydrogen transfer reaction from the alcohols to the olefins takes place alongside the main reaction. With primary alcohols the aldehydes formed are decarbonylated and the in situ catalysts formed from [Rh(diene)Cl]2 and phosphines are partially converted into Rh(CO)(PR3)2Cl type complexes and thereby deactivated.

AB - In the hydrogenation of olefins in alcoholic solvents catalysed by phosphinerhodium complexes a hydrogen transfer reaction from the alcohols to the olefins takes place alongside the main reaction. With primary alcohols the aldehydes formed are decarbonylated and the in situ catalysts formed from [Rh(diene)Cl]2 and phosphines are partially converted into Rh(CO)(PR3)2Cl type complexes and thereby deactivated.

UR - http://www.scopus.com/inward/record.url?scp=33646430784&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=33646430784&partnerID=8YFLogxK

U2 - 10.1016/S0022-328X(00)94429-2

DO - 10.1016/S0022-328X(00)94429-2

M3 - Article

AN - SCOPUS:33646430784

VL - 192

SP - 253

EP - 256

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 2

ER -