Nucleophilic ring cleavage of crown ethers, novel method for building up crown ether rings

Research output: Article

3 Citations (Scopus)

Abstract

The crown ether rings in 4-nitrobenzo-15-crown-5 and -18-crown-6 are cleaved by aqueous alkali affording long chain substituted pyrocatechols which proved to be good starting material for constructing crown ether rings other than the original one.

Original languageEnglish
Pages (from-to)2705-2708
Number of pages4
JournalTetrahedron Letters
Volume26
Issue number22
DOIs
Publication statusPublished - 1985

Fingerprint

Crown Ethers
Catechols
Alkalies
18-crown-6
15-crown-5

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

@article{ccc968fec88444339c0a869338de5189,
title = "Nucleophilic ring cleavage of crown ethers, novel method for building up crown ether rings",
abstract = "The crown ether rings in 4-nitrobenzo-15-crown-5 and -18-crown-6 are cleaved by aqueous alkali affording long chain substituted pyrocatechols which proved to be good starting material for constructing crown ether rings other than the original one.",
author = "B. {\'A}gai and I. Bitter and Z. Hell and A. Sz{\"o}ll{\"o}sy and L. Tőke",
year = "1985",
doi = "10.1016/S0040-4039(00)98142-5",
language = "English",
volume = "26",
pages = "2705--2708",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "22",

}

TY - JOUR

T1 - Nucleophilic ring cleavage of crown ethers, novel method for building up crown ether rings

AU - Ágai, B.

AU - Bitter, I.

AU - Hell, Z.

AU - Szöllösy, A.

AU - Tőke, L.

PY - 1985

Y1 - 1985

N2 - The crown ether rings in 4-nitrobenzo-15-crown-5 and -18-crown-6 are cleaved by aqueous alkali affording long chain substituted pyrocatechols which proved to be good starting material for constructing crown ether rings other than the original one.

AB - The crown ether rings in 4-nitrobenzo-15-crown-5 and -18-crown-6 are cleaved by aqueous alkali affording long chain substituted pyrocatechols which proved to be good starting material for constructing crown ether rings other than the original one.

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U2 - 10.1016/S0040-4039(00)98142-5

DO - 10.1016/S0040-4039(00)98142-5

M3 - Article

AN - SCOPUS:46549101524

VL - 26

SP - 2705

EP - 2708

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 22

ER -