Novel stereocontrolled syntheses of tashiromine and epitashiromine

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8 Citations (Scopus)

Abstract

A novel stereocontrolled approach has been developed for the syntheses of tashiromine and epitashiromine alkaloids from cyclooctene β-amino acids. The synthetic concept is based on the azetidinone opening of a bicyclic β-lactam, followed by oxidative ring opening through ring C-C double bond and reductive ring-closure reactions of the cis- or trans-cyclooctene β-amino acids.

Original languageEnglish
Pages (from-to)596-603
Number of pages8
JournalBeilstein Journal of Organic Chemistry
Volume11
DOIs
Publication statusPublished - ápr. 30 2015

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ASJC Scopus subject areas

  • Organic Chemistry

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