Novel and simple synthesis of carboxyl-terminated polyisobutylenes

Miklós Nagy, S. Kéki, László Orosz, G. Deák, P. Herczegh, A. Lévai, M. Zsuga

Research output: Article

9 Citations (Scopus)

Abstract

The new, simple and effective synthetic methods for the preparation of carboxyl-terminated polyisobutylenes were discussed. It was found that such polymers can serve as valuable starting materials for a number of polymer analog reactions as well as building blocks for the synthesis of block copolymers and networks. Carboxyl derivatives such as anhydrides, nitriles and acid halides are easy to prepare and are more reactive than the carboxyl group. Detailed NMR and matrix-assisted laser desorption/ionization mass spectrometric (MALDI-TOF MS) investigations showed the complete conversion of the starting aldehyde termini into the corresponding carboxyl derivative.

Original languageEnglish
Pages (from-to)4043-4046
Number of pages4
JournalMacromolecules
Volume38
Issue number10
DOIs
Publication statusPublished - máj. 17 2005

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Polymers
Derivatives
Nitriles
Anhydrides
Aldehydes
Block copolymers
Ionization
Desorption
Nuclear magnetic resonance
Acids
Lasers

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Novel and simple synthesis of carboxyl-terminated polyisobutylenes. / Nagy, Miklós; Kéki, S.; Orosz, László; Deák, G.; Herczegh, P.; Lévai, A.; Zsuga, M.

In: Macromolecules, Vol. 38, No. 10, 17.05.2005, p. 4043-4046.

Research output: Article

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AU - Lévai, A.

AU - Zsuga, M.

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