Kinetics of addition and allyl-hydrogen abstraction in the reaction between methyl radicals and 1-heptene

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2 Citations (Scopus)

Abstract

The rates for reactions between methyl radicals and 1-heptene have been studied and the kinetic parameters log (k1/dm3 mol-1s-1)=8.4±0.1-(33.3±1.0) kJ/RT In 10 and log (k3/dm3 mol-1s-1)=7.5±0.2)-29.7±1.5) kJ/RT In 10 have been determined for addition and allyl-hydrogen abstraction, respectively.

Original languageEnglish
Pages (from-to)413-416
Number of pages4
JournalReaction Kinetics and Catalysis Letters
Volume24
Issue number3-4
DOIs
Publication statusPublished - 1984

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Kinetic parameters
Hydrogen
Kinetics
kinetics
hydrogen
methyl radical

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

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title = "Kinetics of addition and allyl-hydrogen abstraction in the reaction between methyl radicals and 1-heptene",
abstract = "The rates for reactions between methyl radicals and 1-heptene have been studied and the kinetic parameters log (k1/dm3 mol-1s-1)=8.4±0.1-(33.3±1.0) kJ/RT In 10 and log (k3/dm3 mol-1s-1)=7.5±0.2)-29.7±1.5) kJ/RT In 10 have been determined for addition and allyl-hydrogen abstraction, respectively.",
author = "S. D{\'o}b{\'e} and F. R{\'e}ti and T. B{\'e}rces",
year = "1984",
doi = "10.1007/BF02093467",
language = "English",
volume = "24",
pages = "413--416",
journal = "Reaction Kinetics, Mechanisms and Catalysis",
issn = "1878-5190",
publisher = "Springer Netherlands",
number = "3-4",

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TY - JOUR

T1 - Kinetics of addition and allyl-hydrogen abstraction in the reaction between methyl radicals and 1-heptene

AU - Dóbé, S.

AU - Réti, F.

AU - Bérces, T.

PY - 1984

Y1 - 1984

N2 - The rates for reactions between methyl radicals and 1-heptene have been studied and the kinetic parameters log (k1/dm3 mol-1s-1)=8.4±0.1-(33.3±1.0) kJ/RT In 10 and log (k3/dm3 mol-1s-1)=7.5±0.2)-29.7±1.5) kJ/RT In 10 have been determined for addition and allyl-hydrogen abstraction, respectively.

AB - The rates for reactions between methyl radicals and 1-heptene have been studied and the kinetic parameters log (k1/dm3 mol-1s-1)=8.4±0.1-(33.3±1.0) kJ/RT In 10 and log (k3/dm3 mol-1s-1)=7.5±0.2)-29.7±1.5) kJ/RT In 10 have been determined for addition and allyl-hydrogen abstraction, respectively.

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U2 - 10.1007/BF02093467

DO - 10.1007/BF02093467

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SP - 413

EP - 416

JO - Reaction Kinetics, Mechanisms and Catalysis

JF - Reaction Kinetics, Mechanisms and Catalysis

SN - 1878-5190

IS - 3-4

ER -