Kinetic comparison of enantioselective hydrogenations

A. Tungle, T. Tamai, A. Deak, S. Kemény, A. Györi, T. Máthé, J. Petró

Research output: Article

7 Citations (Scopus)

Abstract

Kinetic investigation of the Pd/carbon-(S)-proline system in reduction of isophorone and acetophenone and comparison with known enantioselective hydrogenations were camed out. An addition reaction of (S)-proline with the substrates, and the selective hydrogenation of this adduct results in the optically active products, the kinetic analysis verified this mode of action: these are rather diastereoselective reactions.

Original languageEnglish
Pages (from-to)99-106
Number of pages8
JournalStudies in Surface Science and Catalysis
Volume78
Issue numberC
DOIs
Publication statusPublished - jan. 1 1993

ASJC Scopus subject areas

  • Catalysis
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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