Abstract
A series of [3]ferrocenophanes with functional P-E-P motifs (E = group 14 fragments) is reported. Out of these, the silicon compounds with the general formula Fe(C5H4PtBu)2SiXY (XY = Cl2, Br2, I2, H2, HCl) have been characterized by spectroscopic means and the bonding situation was analyzed using X-ray crystallography and quantum chemical calculations. Despite the two stereogenic phosphanyl centers, most of the [3]ferrocenophanes have been obtained as single isomers in the course of stereospecific reactions. The corresponding stannylene Fe(C5H4PtBu)2Sn has been obtained in the form of its dimeric adduct.
| Original language | English |
|---|---|
| Pages (from-to) | 2180-2189 |
| Number of pages | 10 |
| Journal | Dalton Transactions |
| Volume | 45 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - 2016 |
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ASJC Scopus subject areas
- Inorganic Chemistry
Cite this
Ferrocenophanes with the bisphosphanotetryl bridge : Inorganic rings on the way to tetrylenes. / Kargin, Denis; Kelemen, Zsolt; Krekić, Kristijan; Maurer, Martin; Bruhn, Clemens; Nyulászi, L.; Pietschnig, Rudolf.
In: Dalton Transactions, Vol. 45, No. 5, 2016, p. 2180-2189.Research output: Article
}
TY - JOUR
T1 - Ferrocenophanes with the bisphosphanotetryl bridge
T2 - Inorganic rings on the way to tetrylenes
AU - Kargin, Denis
AU - Kelemen, Zsolt
AU - Krekić, Kristijan
AU - Maurer, Martin
AU - Bruhn, Clemens
AU - Nyulászi, L.
AU - Pietschnig, Rudolf
PY - 2016
Y1 - 2016
N2 - A series of [3]ferrocenophanes with functional P-E-P motifs (E = group 14 fragments) is reported. Out of these, the silicon compounds with the general formula Fe(C5H4PtBu)2SiXY (XY = Cl2, Br2, I2, H2, HCl) have been characterized by spectroscopic means and the bonding situation was analyzed using X-ray crystallography and quantum chemical calculations. Despite the two stereogenic phosphanyl centers, most of the [3]ferrocenophanes have been obtained as single isomers in the course of stereospecific reactions. The corresponding stannylene Fe(C5H4PtBu)2Sn has been obtained in the form of its dimeric adduct.
AB - A series of [3]ferrocenophanes with functional P-E-P motifs (E = group 14 fragments) is reported. Out of these, the silicon compounds with the general formula Fe(C5H4PtBu)2SiXY (XY = Cl2, Br2, I2, H2, HCl) have been characterized by spectroscopic means and the bonding situation was analyzed using X-ray crystallography and quantum chemical calculations. Despite the two stereogenic phosphanyl centers, most of the [3]ferrocenophanes have been obtained as single isomers in the course of stereospecific reactions. The corresponding stannylene Fe(C5H4PtBu)2Sn has been obtained in the form of its dimeric adduct.
UR - http://www.scopus.com/inward/record.url?scp=84956698140&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84956698140&partnerID=8YFLogxK
U2 - 10.1039/c5dt03107a
DO - 10.1039/c5dt03107a
M3 - Article
AN - SCOPUS:84956698140
VL - 45
SP - 2180
EP - 2189
JO - Dalton Transactions
JF - Dalton Transactions
SN - 1477-9226
IS - 5
ER -