Facile and Selective Carbonylation of Methane in Superacids

Peter J F De Rege, John A. Gladysz, I. Horváth

Research output: Article

14 Citations (Scopus)

Abstract

The carbonylation of CH4 with carbon monoxide in superacids HF/SbF5 or HSO3F/SbF5 leads to the exclusive and quantitative formation of the acylium ion ([CH3CO]+[SbF6]-) with the concomitant stoichiometric formation of SbF3.

Original languageEnglish
Pages (from-to)1059-1062
Number of pages4
JournalAdvanced Synthesis and Catalysis
Volume344
Issue number10
DOIs
Publication statusPublished - dec. 2002

Fingerprint

Carbonylation
Methane
Carbon Monoxide
Carbon monoxide
Ions

ASJC Scopus subject areas

  • Catalysis
  • Chemistry (miscellaneous)
  • Organic Chemistry

Cite this

Facile and Selective Carbonylation of Methane in Superacids. / De Rege, Peter J F; Gladysz, John A.; Horváth, I.

In: Advanced Synthesis and Catalysis, Vol. 344, No. 10, 12.2002, p. 1059-1062.

Research output: Article

De Rege, PJF, Gladysz, JA & Horváth, I 2002, 'Facile and Selective Carbonylation of Methane in Superacids', Advanced Synthesis and Catalysis, vol. 344, no. 10, pp. 1059-1062. https://doi.org/10.1002/1615-4169(200212)344:10<1059::AID-ADSC1059>3.0.CO;2-O
De Rege PJF, Gladysz JA, Horváth I. Facile and Selective Carbonylation of Methane in Superacids. Advanced Synthesis and Catalysis. 2002 dec.;344(10):1059-1062. https://doi.org/10.1002/1615-4169(200212)344:10<1059::AID-ADSC1059>3.0.CO;2-O
De Rege, Peter J F ; Gladysz, John A. ; Horváth, I. / Facile and Selective Carbonylation of Methane in Superacids. In: Advanced Synthesis and Catalysis. 2002 ; Vol. 344, No. 10. pp. 1059-1062.
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