(E/Z)-isomerization of 3′-epilutein

Research output: Article

6 Citations (Scopus)

Abstract

3′-Epilutein (=(all-E,3R,3′S,6′R)-4′,5′- didehydro-5′,6′-dihydro-β,β-carotene-3,3′-diol; 1), isolated from the flowers of Caltha palustris, was submitted to both thermal isomerization and I2-catalyzed photoisomerization. The structures of the main products; (9Z)-1, (9′Z)-1, (13Z)-1, (13′Z)-1, (15Z)-1, and (9Z,9′Z)-1 were determined based on UV/VIS, CD, 1H-NMR, and MS data.

Original languageEnglish
Pages (from-to)2169-2179
Number of pages11
JournalHelvetica Chimica Acta
Volume87
Issue number8
DOIs
Publication statusPublished - okt. 4 2004

ASJC Scopus subject areas

  • Catalysis
  • Biochemistry
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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