Evaluation of catalytic activity of [RuClCp(dmoPTA)(PPh3)](OSO2CF3) in the isomerization of allylic alcohols in water (dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane)

Adrian Mena-Cruz, Manuel Serrano-Ruiz, Pablo Lorenzo-Luis, Antonio Romerosa, Ágnes Kathó, Ferenc Joó, Luis Manuel Aguilera-Sáez

Research output: Article

15 Citations (Scopus)

Abstract

The catalytic activity of [RuClCp(HdmoPTA)(PPh3)](OSO2CF3) (1) and the dimeric complexes [RuClCp(PPh3)-μ-dmoPTA-1κP:2κ2N,N'-MCl2] (M = Ni (2), Co (3), Zn (4)) for the isomerization in water under Ar and ambient atmosphere of 1-octen-3-ol, 1-hepten-3-ol and 1-hexen-3-ol was investigated. A detailed study was devoted to the catalytic activity under Ar of 1 for the isomerization of 1-octen-3-ol.

Original languageEnglish
Pages (from-to)27-33
Number of pages7
JournalJournal of Molecular Catalysis A: Chemical
Volume411
DOIs
Publication statusPublished - okt. 8 2016

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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