Ethyl (O-B)-5-(difluoroboryloxy)tricyclo-[4.3.1.13,8 ]undecane-4- carboxylate

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Abstract

The title compound, C14H19BF2O 3, can be described as a resonance hybrid. The entering BF 2 moiety interacts with the C=O (oxo) groups of the parent compound, 5-(ethoxy-carbonyl)adamantan-4-one, generating two conjugated double bonds in the six-membered difluorodioxoborane ring. In spite of the conjugation between the multiple bonds, the tetrahedral configuration of the B atom gives rise to a non-planar conformation of the six-membered ring, which assumes a state intermediate between the boat and sofa forms.

Original languageEnglish
Pages (from-to)o1554-o1555
JournalActa Crystallographica Section E: Structure Reports Online
Volume59
Issue number10
DOIs
Publication statusPublished - okt. 1 2003

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ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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