Direct rate constant for the reaction of OH radicals with the biofuel molecule ethyl levulinate

Mária Farkas, Ádám Illés, Balázs Petri, Sándor Dóbé

Research output: Article

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Abstract

Second generation (2G) biofuels are produced from non-edible ligno-cellulosic biomass providing sustainable alternatives for fossil fuels. The OH reaction rate constant has been determined for the 2G biofuel ethyl levulinate (CH 3 C(O)CH 2 CH 2 C(O)OCH 2 CH 3 , ELA) (1) for the first time. The direct reaction kinetic technique of pulsed laser photolysis (PLP) coupled with resonance fluorescence (RF) detection of OH radicals has been used to determine the rate constant value of k 1 = (3.43 ± 0.36) × 10 -12 cm 3 molecule -1 s -1 (298 K), where the error given designates 2σ accuracy. Implications for atmospheric chemistry have been discussed.

Original languageEnglish
Pages (from-to)251-257
Number of pages7
JournalReaction Kinetics, Mechanisms and Catalysis
Volume104
Issue number2
DOIs
Publication statusPublished - dec. 2011

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ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

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