Conformational studies of nitroxide radicals by esr spectroscopy. Part III. Comparison of one and more-than-one conformation models for the hindered rotations of methine group

P. Simon, A. Rockenbauer

Research output: Article

Abstract

Conformations of aryl-methine nitroxides have been investigated through the temperature dependence of N-methine proton hyperfine coupling. The proposed model consists of several conformations with interconversional equilibrium and internal torsion oscillations.

Original languageEnglish
Pages (from-to)159-162
Number of pages4
JournalJournal of Molecular Structure
Volume140
Issue number1-2
DOIs
Publication statusPublished - 1986

Fingerprint

torsion
Conformations
Protons
Spectrum Analysis
Spectroscopy
temperature dependence
oscillations
Temperature
protons
Torsional stress
spectroscopy
nitroxyl

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

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title = "Conformational studies of nitroxide radicals by esr spectroscopy. Part III. Comparison of one and more-than-one conformation models for the hindered rotations of methine group",
abstract = "Conformations of aryl-methine nitroxides have been investigated through the temperature dependence of N-methine proton hyperfine coupling. The proposed model consists of several conformations with interconversional equilibrium and internal torsion oscillations.",
author = "P. Simon and A. Rockenbauer",
year = "1986",
doi = "10.1016/0022-2860(86)80158-2",
language = "English",
volume = "140",
pages = "159--162",
journal = "Journal of Molecular Structure",
issn = "0022-2860",
publisher = "Elsevier",
number = "1-2",

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AU - Simon, P.

AU - Rockenbauer, A.

PY - 1986

Y1 - 1986

N2 - Conformations of aryl-methine nitroxides have been investigated through the temperature dependence of N-methine proton hyperfine coupling. The proposed model consists of several conformations with interconversional equilibrium and internal torsion oscillations.

AB - Conformations of aryl-methine nitroxides have been investigated through the temperature dependence of N-methine proton hyperfine coupling. The proposed model consists of several conformations with interconversional equilibrium and internal torsion oscillations.

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U2 - 10.1016/0022-2860(86)80158-2

DO - 10.1016/0022-2860(86)80158-2

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JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

SN - 0022-2860

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