Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions

V. N. Popok, R. I. Khaibullin, A. Tóth, V. Beshliu, V. Hnatowicz, A. Mackova

Research output: Article

20 Citations (Scopus)

Abstract

Polyimide (PI) foils were implanted with 40 keV Fe+ and Co+ ions to the fluences of 2.5 × 1016-1.25 × 1017 cm-2 at the ion current densities of 4, 8 and 12 μAcm-2. Surface morphology and compositional alteration of the implanted polymer have been studied using atomic force microscopy, transmission electron microscopy, Rutherford backscattering and X-ray photoelectron spectroscopy. Carbonisation of the surface layer, followed by oxygen and nitrogen depletion is observed. These processes reach the saturation level at the applied high fluences. A further increase of ion fluence and density of ion current does not change the composition; only an increase in the metal concentration is observed. It is shown that metal ion implantation to high fluence at high ion current density can be effectively employed to form metal/polymer nanocomposites with required parameters.

Original languageEnglish
Pages (from-to)1034-1039
Number of pages6
JournalSurface Science
Volume532-535
DOIs
Publication statusPublished - jún. 10 2003

Fingerprint

polyimides
Polyimides
Ion implantation
implantation
fluence
Ions
ion currents
ions
current density
Polymers
Current density
Metals
carbonization
polymers
metals
Carbonization
Rutherford backscattering spectroscopy
ion implantation
foils
metal ions

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces

Cite this

Popok, V. N., Khaibullin, R. I., Tóth, A., Beshliu, V., Hnatowicz, V., & Mackova, A. (2003). Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions. Surface Science, 532-535, 1034-1039. https://doi.org/10.1016/S0039-6028(03)00408-4

Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions. / Popok, V. N.; Khaibullin, R. I.; Tóth, A.; Beshliu, V.; Hnatowicz, V.; Mackova, A.

In: Surface Science, Vol. 532-535, 10.06.2003, p. 1034-1039.

Research output: Article

Popok, VN, Khaibullin, RI, Tóth, A, Beshliu, V, Hnatowicz, V & Mackova, A 2003, 'Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions', Surface Science, vol. 532-535, pp. 1034-1039. https://doi.org/10.1016/S0039-6028(03)00408-4
Popok, V. N. ; Khaibullin, R. I. ; Tóth, A. ; Beshliu, V. ; Hnatowicz, V. ; Mackova, A. / Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions. In: Surface Science. 2003 ; Vol. 532-535. pp. 1034-1039.
@article{5f2f81c3e7e74d74a403a13532651662,
title = "Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions",
abstract = "Polyimide (PI) foils were implanted with 40 keV Fe+ and Co+ ions to the fluences of 2.5 × 1016-1.25 × 1017 cm-2 at the ion current densities of 4, 8 and 12 μAcm-2. Surface morphology and compositional alteration of the implanted polymer have been studied using atomic force microscopy, transmission electron microscopy, Rutherford backscattering and X-ray photoelectron spectroscopy. Carbonisation of the surface layer, followed by oxygen and nitrogen depletion is observed. These processes reach the saturation level at the applied high fluences. A further increase of ion fluence and density of ion current does not change the composition; only an increase in the metal concentration is observed. It is shown that metal ion implantation to high fluence at high ion current density can be effectively employed to form metal/polymer nanocomposites with required parameters.",
keywords = "Atomic force microscopy, Ion implantation, Radiation damage, Surface structure, morphology, roughness, and topography, X-ray photoelectron spectroscopy",
author = "Popok, {V. N.} and Khaibullin, {R. I.} and A. T{\'o}th and V. Beshliu and V. Hnatowicz and A. Mackova",
year = "2003",
month = "6",
day = "10",
doi = "10.1016/S0039-6028(03)00408-4",
language = "English",
volume = "532-535",
pages = "1034--1039",
journal = "Surface Science",
issn = "0039-6028",
publisher = "Elsevier",

}

TY - JOUR

T1 - Compositional alteration of polyimide under high fluence implantation by Co+ and Fe+ ions

AU - Popok, V. N.

AU - Khaibullin, R. I.

AU - Tóth, A.

AU - Beshliu, V.

AU - Hnatowicz, V.

AU - Mackova, A.

PY - 2003/6/10

Y1 - 2003/6/10

N2 - Polyimide (PI) foils were implanted with 40 keV Fe+ and Co+ ions to the fluences of 2.5 × 1016-1.25 × 1017 cm-2 at the ion current densities of 4, 8 and 12 μAcm-2. Surface morphology and compositional alteration of the implanted polymer have been studied using atomic force microscopy, transmission electron microscopy, Rutherford backscattering and X-ray photoelectron spectroscopy. Carbonisation of the surface layer, followed by oxygen and nitrogen depletion is observed. These processes reach the saturation level at the applied high fluences. A further increase of ion fluence and density of ion current does not change the composition; only an increase in the metal concentration is observed. It is shown that metal ion implantation to high fluence at high ion current density can be effectively employed to form metal/polymer nanocomposites with required parameters.

AB - Polyimide (PI) foils were implanted with 40 keV Fe+ and Co+ ions to the fluences of 2.5 × 1016-1.25 × 1017 cm-2 at the ion current densities of 4, 8 and 12 μAcm-2. Surface morphology and compositional alteration of the implanted polymer have been studied using atomic force microscopy, transmission electron microscopy, Rutherford backscattering and X-ray photoelectron spectroscopy. Carbonisation of the surface layer, followed by oxygen and nitrogen depletion is observed. These processes reach the saturation level at the applied high fluences. A further increase of ion fluence and density of ion current does not change the composition; only an increase in the metal concentration is observed. It is shown that metal ion implantation to high fluence at high ion current density can be effectively employed to form metal/polymer nanocomposites with required parameters.

KW - Atomic force microscopy

KW - Ion implantation

KW - Radiation damage

KW - Surface structure, morphology, roughness, and topography

KW - X-ray photoelectron spectroscopy

UR - http://www.scopus.com/inward/record.url?scp=0038137561&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038137561&partnerID=8YFLogxK

U2 - 10.1016/S0039-6028(03)00408-4

DO - 10.1016/S0039-6028(03)00408-4

M3 - Article

AN - SCOPUS:0038137561

VL - 532-535

SP - 1034

EP - 1039

JO - Surface Science

JF - Surface Science

SN - 0039-6028

ER -