Chemical reactions in fast atom bombardment mass spectrometry

K. Vékey, Luigi F. Zerilli

Research output: Article

26 Citations (Scopus)

Abstract

Examples of various chemical reactions occurring in the matrix or in the selvedge region in fast atom bombardment (FAB) mass spectrometry are discussed. These are categorized as oxidations and reductions; substitutions; clusterings and additions; and sample decomposition or transformation. Some reactions observed showed significant time behaviour and in one case it was possible to determine rate constants. These data suggest that chemical reactions can be accelerated significantly by fast atom bombardment.

Original languageEnglish
Pages (from-to)939-944
Number of pages6
JournalOrganic Mass Spectrometry
Volume26
Issue number11
DOIs
Publication statusPublished - 1991

Fingerprint

Fast Atom Bombardment Mass Spectrometry
Oxidation-Reduction
Mass spectrometry
Cluster Analysis
bombardment
Chemical reactions
chemical reactions
mass spectroscopy
Atoms
atoms
Rate constants
Substitution reactions
substitutes
Decomposition
decomposition
Oxidation
oxidation
matrices

ASJC Scopus subject areas

  • Biochemistry
  • Molecular Medicine
  • Instrumentation

Cite this

Chemical reactions in fast atom bombardment mass spectrometry. / Vékey, K.; Zerilli, Luigi F.

In: Organic Mass Spectrometry, Vol. 26, No. 11, 1991, p. 939-944.

Research output: Article

Vékey, K. ; Zerilli, Luigi F. / Chemical reactions in fast atom bombardment mass spectrometry. In: Organic Mass Spectrometry. 1991 ; Vol. 26, No. 11. pp. 939-944.
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