CD spectroscopic study of absolute conformation and configuration of some 4-hydroxychromans

Zs. Majer, M. Hollósi, A. Lévai, Maja Majerić, Vitomir Šunjić

Research output: Article

6 Citations (Scopus)

Abstract

CD data of the optically active 4-hydroxy (1–5) and 4-acetoxy chromans (6–8) were analyzed by two different approaches. The Snatzke-Antus treatment of chiraly perturbed chromane chromophore revealed M absolute conformation and 4S absolute configuration of the alcohols, i.e. P absolute conformation and 4R absolute configuration of the acetates. The proposed absolute configuration of the optically active alcohols was confirmed for 1 and 2 by the chiral excitone coupling method applied on their benzoates 9 and 10.

Original languageEnglish
Pages (from-to)1181-1190
Number of pages10
JournalSpectroscopy Letters
Volume28
Issue number8
DOIs
Publication statusPublished - dec. 1 1995

Fingerprint

Conformations
Chromans
Alcohols
Benzoates
alcohols
Chromophores
configurations
Acetates
chromophores
acetates

ASJC Scopus subject areas

  • Analytical Chemistry
  • Spectroscopy
  • Atomic and Molecular Physics, and Optics

Cite this

CD spectroscopic study of absolute conformation and configuration of some 4-hydroxychromans. / Majer, Zs.; Hollósi, M.; Lévai, A.; Majerić, Maja; Šunjić, Vitomir.

In: Spectroscopy Letters, Vol. 28, No. 8, 01.12.1995, p. 1181-1190.

Research output: Article

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AU - Šunjić, Vitomir

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