Adoption and evaluation of a sample pretreatment protocol for radiocarbon dating of cremated bones at HEKAL

István Major, János Dani, Viktória Kiss, Eszter Melis, Róbert Patay, Géza Szabó, Katalin Hubay, Marianna Túri, I. Futó, R. Huszánk, A. J.Timothy Jull, Mihály Molnár

Research output: Article

Abstract

A comparative study was undertaken to adopt and evaluate a radiocarbon ( 14 C) preparation procedure for accelerator mass spectrometry (AMS) measurements of cremated bones at our laboratory, including different types of archaeological samples (cremated bone, bone, charcoal, charred grain). All 14 C analyses were performed using the EnvironMICADAS AMS instrument at the Hertelendi Laboratory of Environmental Studies (HEKAL) and the ancillary analyses were also performed at the Institute for Nuclear Research (ATOMKI). After the physical and chemical cleaning of cremated bones, CO2 was extracted by acid hydrolysis followed by sealed-tube graphitization and 14 C measurement. The supplementary δ 13 C measurements were also performed on CO2 gas while FTIR was measured on the powder fraction. Based on the FTIR and 14 C analyses, our chemical pretreatment protocol was successful in removing contamination from the samples. Good reproducibility was obtained for the 0.2-0.3 mm fraction of blind-tested cremated samples and a maximum age difference of only 150 yr was found for the remaining case studies. This confirms the reliability of our procedure for 14 C dating of cremated bones. However, in one case study, the age difference of 300 yr between two cremated fragments originating from the same urn shows that other processes affecting the cremated samples in the post-burial environment can substantially influence the 14 C age, so caution must be exercised.

Original languageEnglish
Pages (from-to)159-171
Number of pages13
JournalRadiocarbon
Volume61
Issue number1
DOIs
Publication statusPublished - febr. 1 2019

Fingerprint

radiocarbon dating
bone
accelerator mass spectrometry
graphitization
charcoal
hydrolysis
comparative study
evaluation
protocol
Evaluation
Pretreatment
Radiocarbon Dating
Cremated Bones
acid
gas
laboratory
chemical

Keywords

    ASJC Scopus subject areas

    • Archaeology
    • Earth and Planetary Sciences(all)

    Cite this

    Major, I., Dani, J., Kiss, V., Melis, E., Patay, R., Szabó, G., ... Molnár, M. (2019). Adoption and evaluation of a sample pretreatment protocol for radiocarbon dating of cremated bones at HEKAL. Radiocarbon, 61(1), 159-171. https://doi.org/10.1017/RDC.2018.41

    Adoption and evaluation of a sample pretreatment protocol for radiocarbon dating of cremated bones at HEKAL. / Major, István; Dani, János; Kiss, Viktória; Melis, Eszter; Patay, Róbert; Szabó, Géza; Hubay, Katalin; Túri, Marianna; Futó, I.; Huszánk, R.; Jull, A. J.Timothy; Molnár, Mihály.

    In: Radiocarbon, Vol. 61, No. 1, 01.02.2019, p. 159-171.

    Research output: Article

    Major, I, Dani, J, Kiss, V, Melis, E, Patay, R, Szabó, G, Hubay, K, Túri, M, Futó, I, Huszánk, R, Jull, AJT & Molnár, M 2019, 'Adoption and evaluation of a sample pretreatment protocol for radiocarbon dating of cremated bones at HEKAL' Radiocarbon, vol. 61, no. 1, pp. 159-171. https://doi.org/10.1017/RDC.2018.41
    Major, István ; Dani, János ; Kiss, Viktória ; Melis, Eszter ; Patay, Róbert ; Szabó, Géza ; Hubay, Katalin ; Túri, Marianna ; Futó, I. ; Huszánk, R. ; Jull, A. J.Timothy ; Molnár, Mihály. / Adoption and evaluation of a sample pretreatment protocol for radiocarbon dating of cremated bones at HEKAL. In: Radiocarbon. 2019 ; Vol. 61, No. 1. pp. 159-171.
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    abstract = "A comparative study was undertaken to adopt and evaluate a radiocarbon ( 14 C) preparation procedure for accelerator mass spectrometry (AMS) measurements of cremated bones at our laboratory, including different types of archaeological samples (cremated bone, bone, charcoal, charred grain). All 14 C analyses were performed using the EnvironMICADAS AMS instrument at the Hertelendi Laboratory of Environmental Studies (HEKAL) and the ancillary analyses were also performed at the Institute for Nuclear Research (ATOMKI). After the physical and chemical cleaning of cremated bones, CO2 was extracted by acid hydrolysis followed by sealed-tube graphitization and 14 C measurement. The supplementary δ 13 C measurements were also performed on CO2 gas while FTIR was measured on the powder fraction. Based on the FTIR and 14 C analyses, our chemical pretreatment protocol was successful in removing contamination from the samples. Good reproducibility was obtained for the 0.2-0.3 mm fraction of blind-tested cremated samples and a maximum age difference of only 150 yr was found for the remaining case studies. This confirms the reliability of our procedure for 14 C dating of cremated bones. However, in one case study, the age difference of 300 yr between two cremated fragments originating from the same urn shows that other processes affecting the cremated samples in the post-burial environment can substantially influence the 14 C age, so caution must be exercised.",
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