2‐(Hydroxymethyl)androstene Derivatives

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Abstract

3‐Hydroxy‐2‐hydroxymethyl‐ (2 and 3) and 3‐hydroxymethyl‐3‐oxoandrostenes 4 were prepared from 2‐hydroxymethylene derivatives 1. The configurations of the chiral centers were determined on the basis of chiroptical, spectroscopical, and X‐ray analytical data. Furthermore, elimination reaction products (5, 6) were identified.

Original languageEnglish
Pages (from-to)499-504
Number of pages6
JournalLiebigs Annalen der Chemie
Volume1987
Issue number6
DOIs
Publication statusPublished - 1987

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ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry

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