1,2,3,4,5,6-Hexahydrophosphinine 1-oxides with an exocyclic P-function at position 3: Diastereoselective synthesis, stereostructure and conformation

Research output: Article

19 Citations (Scopus)

Abstract

Catalytic hydrogenation of the corresponding tetrahydrophosphinine oxides afforded the title compounds (4-6) as exclusive or major diastereomers the stereostructure and conformation of which were evaluated by stereospecific 3J couplings, as well as HF/6-31G* ab initio calculations.

Original languageEnglish
Pages (from-to)1655-1658
Number of pages4
JournalTetrahedron Letters
Volume46
Issue number10
DOIs
Publication statusPublished - márc. 7 2005

Fingerprint

Hydrogenation
Oxides
Conformations

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

@article{bcf13ee375b84949a2c22202d34e35b7,
title = "1,2,3,4,5,6-Hexahydrophosphinine 1-oxides with an exocyclic P-function at position 3: Diastereoselective synthesis, stereostructure and conformation",
abstract = "Catalytic hydrogenation of the corresponding tetrahydrophosphinine oxides afforded the title compounds (4-6) as exclusive or major diastereomers the stereostructure and conformation of which were evaluated by stereospecific 3J couplings, as well as HF/6-31G* ab initio calculations.",
keywords = "Conformation, Hydrogenation, Phosphorus heterocycles, Stereoselection",
author = "G. Keglevich and M. Sipos and T. K{\"o}rtv{\'e}lyesi and T. Imre and L. Tőke",
year = "2005",
month = "3",
day = "7",
doi = "10.1016/j.tetlet.2005.01.073",
language = "English",
volume = "46",
pages = "1655--1658",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Elsevier Limited",
number = "10",

}

TY - JOUR

T1 - 1,2,3,4,5,6-Hexahydrophosphinine 1-oxides with an exocyclic P-function at position 3

T2 - Diastereoselective synthesis, stereostructure and conformation

AU - Keglevich, G.

AU - Sipos, M.

AU - Körtvélyesi, T.

AU - Imre, T.

AU - Tőke, L.

PY - 2005/3/7

Y1 - 2005/3/7

N2 - Catalytic hydrogenation of the corresponding tetrahydrophosphinine oxides afforded the title compounds (4-6) as exclusive or major diastereomers the stereostructure and conformation of which were evaluated by stereospecific 3J couplings, as well as HF/6-31G* ab initio calculations.

AB - Catalytic hydrogenation of the corresponding tetrahydrophosphinine oxides afforded the title compounds (4-6) as exclusive or major diastereomers the stereostructure and conformation of which were evaluated by stereospecific 3J couplings, as well as HF/6-31G* ab initio calculations.

KW - Conformation

KW - Hydrogenation

KW - Phosphorus heterocycles

KW - Stereoselection

UR - http://www.scopus.com/inward/record.url?scp=13744260318&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=13744260318&partnerID=8YFLogxK

U2 - 10.1016/j.tetlet.2005.01.073

DO - 10.1016/j.tetlet.2005.01.073

M3 - Article

AN - SCOPUS:13744260318

VL - 46

SP - 1655

EP - 1658

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 10

ER -