π-Extended Phosphepines: Redox and Optically Active P-Heterocycles with Nonplanar Framework

Thomas Delouche, Anabella Mocanu, Thierry Roisnel, Rózsa Szucs, Emmanuel Jacques, Zoltán Benko, L. Nyulászi, Pierre Antoine Bouit, Muriel Hissler

Research output: Article

1 Citation (Scopus)

Abstract

In this letter, we present the synthesis of a new family of π-extended dithieno[b,f]phosphepines. The Pd-catalyzed direct arylation allows the introduction of various substituents, which tune the absorption/emission in the visible range as well as the redox properties. All those modifications were rationalized through DFT calculations. The physical properties of ambipolar phosphepine with diphenylamino substituents inspired us to use it as a semiconductor in p-type organic field-effect transistors (OFETs). ©

Original languageEnglish
Pages (from-to)802-806
Number of pages5
JournalOrganic Letters
Volume21
Issue number3
DOIs
Publication statusPublished - febr. 1 2019

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Organic field effect transistors
Semiconductors
Discrete Fourier transforms
Oxidation-Reduction
field effect transistors
Physical properties
physical properties
Semiconductor materials
synthesis

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Delouche, T., Mocanu, A., Roisnel, T., Szucs, R., Jacques, E., Benko, Z., ... Hissler, M. (2019). π-Extended Phosphepines: Redox and Optically Active P-Heterocycles with Nonplanar Framework. Organic Letters, 21(3), 802-806. https://doi.org/10.1021/acs.orglett.8b04064

π-Extended Phosphepines : Redox and Optically Active P-Heterocycles with Nonplanar Framework. / Delouche, Thomas; Mocanu, Anabella; Roisnel, Thierry; Szucs, Rózsa; Jacques, Emmanuel; Benko, Zoltán; Nyulászi, L.; Bouit, Pierre Antoine; Hissler, Muriel.

In: Organic Letters, Vol. 21, No. 3, 01.02.2019, p. 802-806.

Research output: Article

Delouche, T, Mocanu, A, Roisnel, T, Szucs, R, Jacques, E, Benko, Z, Nyulászi, L, Bouit, PA & Hissler, M 2019, 'π-Extended Phosphepines: Redox and Optically Active P-Heterocycles with Nonplanar Framework', Organic Letters, vol. 21, no. 3, pp. 802-806. https://doi.org/10.1021/acs.orglett.8b04064
Delouche T, Mocanu A, Roisnel T, Szucs R, Jacques E, Benko Z et al. π-Extended Phosphepines: Redox and Optically Active P-Heterocycles with Nonplanar Framework. Organic Letters. 2019 febr. 1;21(3):802-806. https://doi.org/10.1021/acs.orglett.8b04064
Delouche, Thomas ; Mocanu, Anabella ; Roisnel, Thierry ; Szucs, Rózsa ; Jacques, Emmanuel ; Benko, Zoltán ; Nyulászi, L. ; Bouit, Pierre Antoine ; Hissler, Muriel. / π-Extended Phosphepines : Redox and Optically Active P-Heterocycles with Nonplanar Framework. In: Organic Letters. 2019 ; Vol. 21, No. 3. pp. 802-806.
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