X-ray emission spectroscopy investigation of Cu nanoclusters embedded in a C60 fullerene matrix

Radian Popescu, Sorin Poenariu, Peter B. Barna, Rodica Manaila, Esther Belin-Ferre

Research output: Contribution to journalArticle

Abstract

The Cu (3d-4s→2p3/2)Lα X-ray emission band has been measured in Cu nanoclusters, present in a series of Cu/C60 thin-film nanostructures. In comparison with bulk Cu, a negative shift and a narrowing of the Lα band have been noticed. These observations are mainly attributed to a size effect but charge transfer from metal to C60 occurring at interfaces and causing a depletion of the Cu 3d band is also considered.

Original languageEnglish
Pages (from-to)583-590
Number of pages8
JournalPhilosophical Magazine Letters
Volume83
Issue number9
DOIs
Publication statusPublished - Sep 2003

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ASJC Scopus subject areas

  • Condensed Matter Physics

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