Raman and infrared absorption spectra of N,N-dimethylthioformamide, N,N-dimethylthioformamide-d7, N,N-dimethylformamide, N,N-dimethylformamide-d7 and bis(N,N-dimethylthioformamide)mercury(II) perchlorate have been recorded and analyzed. Assignment of the bands has been made based on normal coordinate analysis, theoretical ab initio SCF and density functional calculations, and comparisons with similar molecules. The changes occurring in the vibrational spectra when N,N-dimethylthioformamide molecules coordinate to a metal ion are discussed.
- Bis(N,N-dimethylthioformamide)mercury(II) perchlorate
- Normal coordinate analysis
- Vibrational spectra
ASJC Scopus subject areas