Vibrational spectra of square-planar tetrahalogeno-gold(III), -palladium(II), and -platinum(II) anions in solution

Peter L. Goggin, Janos Mink

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59 Citations (Scopus)

Abstract

I.r. and Raman spectra of the salts R4N[AuX4] [R = Bun or Pnn(n-pentyl), X = Cl or Br] and (R4N)2[MX4] (R = Bun or Pnn; M = Pd, X = Cl; M = Pt, X = Cl or Br) in solution are reported, together with the i.r. spectrum of a solid containing (Bun4N)2[PdBr4] and Raman spectra of aqueous solutions containing the above anions and [PtI4]2-. Studies of the solvent dependence of the Raman frequencies of [AuCl4]- and the cation dependence of vibrational frequencies of solid R4N[AuCl4] (R = Me, Et, Prn, Bun, or Pnn) have also been made. The inactive B2u mode has been deduced as 112 cm-1 from a study of the combination bands of solid Cs[AuCl4]. The most consistent sets of vibrational frequencies have been used to recalculate force constants.

Original languageEnglish
Pages (from-to)1479-1483
Number of pages5
JournalJournal of the Chemical Society, Dalton Transactions
Issue number14
DOIs
Publication statusPublished - 1974

ASJC Scopus subject areas

  • Chemistry(all)

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