Vibrational spectra of monothiocarbamates. I. Assignment and tentative force field of S-methyl-N,N-dimethylthiocarbamate

G. Keresztury, G. Besenyei, S. Holly

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

FT-IR and Raman spectra of S-methyl-N,N-dimethylmonothiocarbamate and its d3-, d6-, d9-, and 13C-substituted isotopomers have been recorded and analysed. Normal coordinate calculations were performed to support the assignment and to derive a simplified valence force field which would be characteristic of the monothiocarbamate moiety, =N(CO)S-, and is consistent with the known bond length vs force constant correlations.

Original languageEnglish
Pages (from-to)237-242
Number of pages6
JournalJournal of Molecular Structure
Volume218
Issue numberC
DOIs
Publication statusPublished - 1990

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Bond length
Vibrational spectra
Carbon Monoxide
vibrational spectra
field theory (physics)
Raman scattering
Raman spectra
valence
dimethylthiocarbamate

ASJC Scopus subject areas

  • Structural Biology
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Materials Science (miscellaneous)
  • Atomic and Molecular Physics, and Optics

Cite this

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abstract = "FT-IR and Raman spectra of S-methyl-N,N-dimethylmonothiocarbamate and its d3-, d6-, d9-, and 13C-substituted isotopomers have been recorded and analysed. Normal coordinate calculations were performed to support the assignment and to derive a simplified valence force field which would be characteristic of the monothiocarbamate moiety, =N(CO)S-, and is consistent with the known bond length vs force constant correlations.",
author = "G. Keresztury and G. Besenyei and S. Holly",
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AU - Keresztury, G.

AU - Besenyei, G.

AU - Holly, S.

PY - 1990

Y1 - 1990

N2 - FT-IR and Raman spectra of S-methyl-N,N-dimethylmonothiocarbamate and its d3-, d6-, d9-, and 13C-substituted isotopomers have been recorded and analysed. Normal coordinate calculations were performed to support the assignment and to derive a simplified valence force field which would be characteristic of the monothiocarbamate moiety, =N(CO)S-, and is consistent with the known bond length vs force constant correlations.

AB - FT-IR and Raman spectra of S-methyl-N,N-dimethylmonothiocarbamate and its d3-, d6-, d9-, and 13C-substituted isotopomers have been recorded and analysed. Normal coordinate calculations were performed to support the assignment and to derive a simplified valence force field which would be characteristic of the monothiocarbamate moiety, =N(CO)S-, and is consistent with the known bond length vs force constant correlations.

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