Vibrational spectra and conformation of cyclic methylsiloxanes

G. Fogarasi, H. Hacker, V. Hoffmann, S. Dobos

Research output: Contribution to journalArticle

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Abstract

Complete vibrational spectra (including far-i.r.) are given for the cyclic methyl-siloxanes from the trimer up to the hexamer. The assignment, given for hexamethylcyclotrisiloxane, is based on a planar structure, but some slight deviations from the strict D3h selection rules can be observed. The conformation of the higher members of the series is investigated in the light of flexibility of the rings.

Original languageEnglish
Pages (from-to)629-639
Number of pages11
JournalSpectrochimica Acta Part A: Molecular Spectroscopy
Volume30
Issue number3
DOIs
Publication statusPublished - 1974

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Vibrational spectra
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Vibrational spectra and conformation of cyclic methylsiloxanes. / Fogarasi, G.; Hacker, H.; Hoffmann, V.; Dobos, S.

In: Spectrochimica Acta Part A: Molecular Spectroscopy, Vol. 30, No. 3, 1974, p. 629-639.

Research output: Contribution to journalArticle

Fogarasi, G. ; Hacker, H. ; Hoffmann, V. ; Dobos, S. / Vibrational spectra and conformation of cyclic methylsiloxanes. In: Spectrochimica Acta Part A: Molecular Spectroscopy. 1974 ; Vol. 30, No. 3. pp. 629-639.
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