Variations in bonding of iron in porous ferrisilicates

Research output: Contribution to journalArticle

Abstract

Bonding strengths of iron species in different micro- and mesoporous ferrisilicates are deduced from analysis of changes in recoilless fractions extracted from various series of in situ spectra. The recoilless fractions for extra-framework ions in microporous Fe-LTA may depend strongly on the conditions. In Fe-FER, containing both framework and extra-framework types of iron, modest changes were detected. In mesoporous Fe-MCM-41 samples variations of the bonding strengths were revealed which can apparently be correlated with the partly amorphous structure of the pore walls in these substances.

Original languageEnglish
Pages (from-to)99-109
Number of pages11
JournalHyperfine Interactions
Volume226
Issue number1-3
DOIs
Publication statusPublished - Apr 2014

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Keywords

  • Bonding strength
  • In situ spectra
  • Porous ferrisilicates
  • Recoilless fractions

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Nuclear and High Energy Physics
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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