Unstable methoxycyclosiloxanes [(CH3O)SiO]n (n = 2, 3): Thermal generation and direct mass spectral studies

J. Tamás, A. Gömöry, I. Besenyei, V. N. Khabashesku, Z. A. Kerzina, N. D. Kagramanov, I. O. Bragilevsky

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5 Citations (Scopus)

Abstract

Direct evidence for formation of unstable methoxy cyclosiloxanes [(CH3O)2SiO]2 (1) and [(CH3O)2SiO]3 (2) in the gas phase has been obtained by a mass-spectral study of the vacuum pyrolysis of 3,3-dimethoxy-6-oxa-3-silabicyclo[3.1.0]hexane (4). Intermediates 1 and 2 have been detected in the mass spectra of the pyrolysis products of 4 as the corresponding molecular ions, and identified from their exact masses and compositions. The metastable transitions recorded by B/E scan show the fragmentation trends of 1, 2 and 4 under electron impact (70 eV). The ionization energies (IE), determined for 1 (8.81 ± 0.1 eV) and 2 (8.50 ± 0.1 eV) are considerably lower than than the IE of linear methoxysubstituted silanes and alkanes.

Original languageEnglish
Pages (from-to)147-152
Number of pages6
JournalJournal of Organometallic Chemistry
Volume387
Issue number2
DOIs
Publication statusPublished - May 1 1990

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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