Unique photoreactivity of mercury(II) 5,10,15,20-tetrakis(4- sulfonatophenyl)porphyrin

Ottó Horváth, Zsolt Valicsek, Arnd Vogler

Research output: Contribution to journalArticle

29 Citations (Scopus)

Abstract

Deviating from coplanar metalloporphyrins, the photochemistry of the kinetically labile, sitting-atop mercury(II) 5,10,15,20-tetrakis(4- sulfonatophenyl)porphyrin complex is characterized by irreversible porphyrin ligand to metal charge transfer and reversible dissociation.

Original languageEnglish
Pages (from-to)854-857
Number of pages4
JournalInorganic Chemistry Communications
Volume7
Issue number7
DOIs
Publication statusPublished - Jul 1 2004

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Keywords

  • Charge transfer
  • Dissociation
  • Mercury
  • Metalloporphyrin
  • Photochemistry
  • Photophysics

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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