Unexpected chlorination of angularly annelated [2.2]paracyclophanes during DDQ oxidation

Lucio Minuti, Aldo Taticchi, Assunta Marrocchi, Daniela Lanari, E. Gács-Baitz, A. Gömöry

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

DDQ treatment of the Diels-Alder products 1 unexpectedly led to chloroderivatives 2. Chlorination did not occur during DDQ treatment of the fully aromatised compounds 3. These results point out that DDQ acted as an oxidant and source of chlorine.

Original languageEnglish
Pages (from-to)949-950
Number of pages2
JournalTetrahedron Letters
Volume46
Issue number6
DOIs
Publication statusPublished - Feb 7 2005

Fingerprint

Chlorination
Halogenation
Chlorine
Oxidants
Oxidation
(2.2)paracyclophane

Keywords

  • [2.2]Paracyclophanes
  • Chlorination
  • Oxidation

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Drug Discovery

Cite this

Unexpected chlorination of angularly annelated [2.2]paracyclophanes during DDQ oxidation. / Minuti, Lucio; Taticchi, Aldo; Marrocchi, Assunta; Lanari, Daniela; Gács-Baitz, E.; Gömöry, A.

In: Tetrahedron Letters, Vol. 46, No. 6, 07.02.2005, p. 949-950.

Research output: Contribution to journalArticle

Minuti, Lucio ; Taticchi, Aldo ; Marrocchi, Assunta ; Lanari, Daniela ; Gács-Baitz, E. ; Gömöry, A. / Unexpected chlorination of angularly annelated [2.2]paracyclophanes during DDQ oxidation. In: Tetrahedron Letters. 2005 ; Vol. 46, No. 6. pp. 949-950.
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