Transition metal complexes with hydrazides and hydrazones. Part 81. X-ray crystal structure of a catena-polybromo (acetone-1-naphthoylhydrazone) copper(II)-copper(I) complex

Agneš Kapor, Béla Ribár, Vukadin M. Leovac, G. Argay, A. Kálmán, Stepan Yu Chundak

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The title compound [Cu3Br4C28H28N4O 2] is a type of polymeric three-centre octahedral-trigonal planar coordination complex. The copper(II) atom located at a centre of symmetry is six-coordinate with two bidentate (N3, O1) ligands of acetone-1-naphthoylhydrazone forming the equatorial plane and two bromine ions in axial positions (Cul-Br1 = 2.946(1)Å). The ligands are in trans positions. The Cu(I) atoms are in trigonal planar coordination by two bridging Br- ions (Cu2-Br2 = 2.412(1)Å, Cu2-Br2* = 2.407(2)Å) which connect two Cu(I) atoms and a third bromine ion shared with the octahedral Cu(II) ion (Cu2-Br1 = 2.304(1)Å). The arrangement forms an infinite chain along the b axis.

Original languageEnglish
Pages (from-to)139-144
Number of pages6
JournalJournal of Coordination Chemistry
Volume38
Issue number1-2
Publication statusPublished - 1996

Fingerprint

hydrazides
Hydrazones
hydrazones
Coordination Complexes
Metal complexes
Acetone
acetone
Transition metals
Copper
Crystal structure
transition metals
Ions
Bromine
X rays
copper
crystal structure
bromine
Atoms
ions
x rays

Keywords

  • Acetone-1-naphthoylhydrazone
  • Bromide
  • Copper
  • Polymer
  • X-ray structure

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Transition metal complexes with hydrazides and hydrazones. Part 81. X-ray crystal structure of a catena-polybromo (acetone-1-naphthoylhydrazone) copper(II)-copper(I) complex. / Kapor, Agneš; Ribár, Béla; Leovac, Vukadin M.; Argay, G.; Kálmán, A.; Chundak, Stepan Yu.

In: Journal of Coordination Chemistry, Vol. 38, No. 1-2, 1996, p. 139-144.

Research output: Contribution to journalArticle

@article{5decc7764d4240c38226578af60c173d,
title = "Transition metal complexes with hydrazides and hydrazones. Part 81. X-ray crystal structure of a catena-polybromo (acetone-1-naphthoylhydrazone) copper(II)-copper(I) complex",
abstract = "The title compound [Cu3Br4C28H28N4O 2] is a type of polymeric three-centre octahedral-trigonal planar coordination complex. The copper(II) atom located at a centre of symmetry is six-coordinate with two bidentate (N3, O1) ligands of acetone-1-naphthoylhydrazone forming the equatorial plane and two bromine ions in axial positions (Cul-Br1 = 2.946(1){\AA}). The ligands are in trans positions. The Cu(I) atoms are in trigonal planar coordination by two bridging Br- ions (Cu2-Br2 = 2.412(1){\AA}, Cu2-Br2* = 2.407(2){\AA}) which connect two Cu(I) atoms and a third bromine ion shared with the octahedral Cu(II) ion (Cu2-Br1 = 2.304(1){\AA}). The arrangement forms an infinite chain along the b axis.",
keywords = "Acetone-1-naphthoylhydrazone, Bromide, Copper, Polymer, X-ray structure",
author = "Agneš Kapor and B{\'e}la Rib{\'a}r and Leovac, {Vukadin M.} and G. Argay and A. K{\'a}lm{\'a}n and Chundak, {Stepan Yu}",
year = "1996",
language = "English",
volume = "38",
pages = "139--144",
journal = "Journal of Coordination Chemistry",
issn = "0095-8972",
publisher = "Taylor and Francis Ltd.",
number = "1-2",

}

TY - JOUR

T1 - Transition metal complexes with hydrazides and hydrazones. Part 81. X-ray crystal structure of a catena-polybromo (acetone-1-naphthoylhydrazone) copper(II)-copper(I) complex

AU - Kapor, Agneš

AU - Ribár, Béla

AU - Leovac, Vukadin M.

AU - Argay, G.

AU - Kálmán, A.

AU - Chundak, Stepan Yu

PY - 1996

Y1 - 1996

N2 - The title compound [Cu3Br4C28H28N4O 2] is a type of polymeric three-centre octahedral-trigonal planar coordination complex. The copper(II) atom located at a centre of symmetry is six-coordinate with two bidentate (N3, O1) ligands of acetone-1-naphthoylhydrazone forming the equatorial plane and two bromine ions in axial positions (Cul-Br1 = 2.946(1)Å). The ligands are in trans positions. The Cu(I) atoms are in trigonal planar coordination by two bridging Br- ions (Cu2-Br2 = 2.412(1)Å, Cu2-Br2* = 2.407(2)Å) which connect two Cu(I) atoms and a third bromine ion shared with the octahedral Cu(II) ion (Cu2-Br1 = 2.304(1)Å). The arrangement forms an infinite chain along the b axis.

AB - The title compound [Cu3Br4C28H28N4O 2] is a type of polymeric three-centre octahedral-trigonal planar coordination complex. The copper(II) atom located at a centre of symmetry is six-coordinate with two bidentate (N3, O1) ligands of acetone-1-naphthoylhydrazone forming the equatorial plane and two bromine ions in axial positions (Cul-Br1 = 2.946(1)Å). The ligands are in trans positions. The Cu(I) atoms are in trigonal planar coordination by two bridging Br- ions (Cu2-Br2 = 2.412(1)Å, Cu2-Br2* = 2.407(2)Å) which connect two Cu(I) atoms and a third bromine ion shared with the octahedral Cu(II) ion (Cu2-Br1 = 2.304(1)Å). The arrangement forms an infinite chain along the b axis.

KW - Acetone-1-naphthoylhydrazone

KW - Bromide

KW - Copper

KW - Polymer

KW - X-ray structure

UR - http://www.scopus.com/inward/record.url?scp=2842519025&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=2842519025&partnerID=8YFLogxK

M3 - Article

VL - 38

SP - 139

EP - 144

JO - Journal of Coordination Chemistry

JF - Journal of Coordination Chemistry

SN - 0095-8972

IS - 1-2

ER -