Transition-Metal-Catalyzed Reactions in Steroid Synthesis

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Abstract

Transition metal catalyzed reactions in steroid synthesis was investigated. Hydrogenation, various carbonylation and coupling reactions, 1-4 additions, and cyclizations were catalyzed by transition-metal complexes. Two diastereomeric binaphthol-type bis-steroidal ligands were used in a Ti-catalyzed Torgov cyclization to produce the C ring of a steroidal framework.

Original languageEnglish
Pages (from-to)4095-4129
Number of pages35
JournalChemical reviews
Volume103
Issue number10
DOIs
Publication statusPublished - Oct 1 2003

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ASJC Scopus subject areas

  • Chemistry(all)

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