Transformation of organic compounds in the presence of metal complexes. I. Transformation of unsaturated alcohols with metal complex catalysts

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Abstract

The transformations of unsaturated alcohols (1-hexen-3-ol,2-penten-4-ol, 1-penten-4-ol and 2 methylenecyclohexanol) were studied under identical experimental conditions in the presence of various Rh and Ru complexes (RhCl(PPh3)3, RhH(PPh3)4, RhCl3 · 3H2O, RhCl3 · 3H2O + PPh3, Rh(COD)Cl2, Rh(COD)Cl2 + PPh3, RhCl2(PPh3)3 and RuH2(PPh3)4). Several aspects of both the unsaturated alcohol and the complex exert considerable effects on the extent of the main reactions; isomerization to ketone and double-bond migration.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume297
Issue number3
DOIs
Publication statusPublished - Dec 24 1985

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crack opening displacement
Coordination Complexes
Metal complexes
organic compounds
Organic compounds
alcohols
Alcohols
catalysts
Catalysts
Isomerization
Ketones
ketones
metals
isomerization
3-hexen-1-ol
chlorotris(triphenylphosphine)rhodium

ASJC Scopus subject areas

  • Biochemistry
  • Chemical Engineering (miscellaneous)
  • Inorganic Chemistry
  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Science (miscellaneous)
  • Materials Chemistry

Cite this

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abstract = "The transformations of unsaturated alcohols (1-hexen-3-ol,2-penten-4-ol, 1-penten-4-ol and 2 methylenecyclohexanol) were studied under identical experimental conditions in the presence of various Rh and Ru complexes (RhCl(PPh3)3, RhH(PPh3)4, RhCl3 · 3H2O, RhCl3 · 3H2O + PPh3, Rh(COD)Cl2, Rh(COD)Cl2 + PPh3, RhCl2(PPh3)3 and RuH2(PPh3)4). Several aspects of both the unsaturated alcohol and the complex exert considerable effects on the extent of the main reactions; isomerization to ketone and double-bond migration.",
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AU - Felföldi, K.

AU - Bartók, M.

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Y1 - 1985/12/24

N2 - The transformations of unsaturated alcohols (1-hexen-3-ol,2-penten-4-ol, 1-penten-4-ol and 2 methylenecyclohexanol) were studied under identical experimental conditions in the presence of various Rh and Ru complexes (RhCl(PPh3)3, RhH(PPh3)4, RhCl3 · 3H2O, RhCl3 · 3H2O + PPh3, Rh(COD)Cl2, Rh(COD)Cl2 + PPh3, RhCl2(PPh3)3 and RuH2(PPh3)4). Several aspects of both the unsaturated alcohol and the complex exert considerable effects on the extent of the main reactions; isomerization to ketone and double-bond migration.

AB - The transformations of unsaturated alcohols (1-hexen-3-ol,2-penten-4-ol, 1-penten-4-ol and 2 methylenecyclohexanol) were studied under identical experimental conditions in the presence of various Rh and Ru complexes (RhCl(PPh3)3, RhH(PPh3)4, RhCl3 · 3H2O, RhCl3 · 3H2O + PPh3, Rh(COD)Cl2, Rh(COD)Cl2 + PPh3, RhCl2(PPh3)3 and RuH2(PPh3)4). Several aspects of both the unsaturated alcohol and the complex exert considerable effects on the extent of the main reactions; isomerization to ketone and double-bond migration.

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