Transformation of organic compounds in the presence of metal complexes. IV. Hydrosilylation of 2- and 4-alkylcyclohexanones on rhodium(I) complexes

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Abstract

The hydrosilylation of 2- and 4-alkylcyclohexanones with Ph2SiH2 was studied under various conditions. The isomeric distribution of the resulting alcohols, i.e. the stereochemistry of the hydrosilylation, is influenced by the position and size of the alkyl groups, the catalyst concentration, the reaction temperature, and the types of ligand attached.

Original languageEnglish
Pages (from-to)411-415
Number of pages5
JournalJournal of Organometallic Chemistry
Volume362
Issue number3
DOIs
Publication statusPublished - May 7 1989

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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