Thiol Ester Aminolysis in Acetonitrile

T. Kömives, A. F. Márton, F. Dutka

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The kinetics of the reactions of p-nitro-phenyl thiolacetate with several amines in acetonitrile was studied. Hydrazine exhibits considerably greater nucleophilicity thanexpected from its pKa value. Common mechanism is suggested for the am inolysis of the thiol ester and its oxygen analogue.

Original languageEnglish
Pages (from-to)138
Number of pages1
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume30
Issue number1-2
DOIs
Publication statusPublished - Feb 1 1975

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hydrazine
Sulfhydryl Compounds
Amines
Esters
Oxygen
Kinetics
acetonitrile

Keywords

  • Alpha Effect
  • Aminolysis
  • Kinetics
  • Mechanism
  • Thiol Ester

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Thiol Ester Aminolysis in Acetonitrile. / Kömives, T.; Márton, A. F.; Dutka, F.

In: Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, Vol. 30, No. 1-2, 01.02.1975, p. 138.

Research output: Contribution to journalArticle

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