Thin-layer chromatography of some methylated amino acids with aqueous salt solutions used as eluents

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Abstract

The retention order of methylated lysine and arginine derivatives followed a reversed-phase separation pattern on various silicas with aqueous salt solutions used as eluents. Principal component analysis established that the origin of the silica exerts a dominant influence on their chromatographic performance, and the effect of impregnation and salt quality are of secondary importance. Good linear correlations were found between the lipophilicity-decreasing effect of monovalent cations and their ionic radii.

Original languageEnglish
Pages (from-to)289-296
Number of pages8
JournalJournal of Chromatography A
Volume365
Issue numberC
DOIs
Publication statusPublished - Sep 19 1986

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ASJC Scopus subject areas

  • Analytical Chemistry
  • Biochemistry
  • Organic Chemistry

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