Thiazole C-nucleosides. V. Remote group participation operating in the reactions of diastereomeric 2-(2′-deoxypent-1′-enopyranosyl)thiazole derivatives

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Abstract

The supposed interplay of remote group participation and anomeric, allylic and stereodirecting effects exerted by different groups are invoked to explain the formation of a new stereocenter in unsaturated thiazole C-nucleosides 5 and 6.

Original languageEnglish
Pages (from-to)1015-1019
Number of pages5
JournalBulletin de la Societe Chimique de France
Volume132
Issue number10
Publication statusPublished - 1995

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Thiazoles
Nucleosides
Derivatives

Keywords

  • conformation
  • remote group participation
  • thiazole C-nucleoside

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Thiazole C-nucleosides. V. Remote group participation operating in the reactions of diastereomeric 2-(2′-deoxypent-1′-enopyranosyl)thiazole derivatives",
abstract = "The supposed interplay of remote group participation and anomeric, allylic and stereodirecting effects exerted by different groups are invoked to explain the formation of a new stereocenter in unsaturated thiazole C-nucleosides 5 and 6.",
keywords = "conformation, remote group participation, thiazole C-nucleoside",
author = "L. Kov{\'a}cs",
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T1 - Thiazole C-nucleosides. V. Remote group participation operating in the reactions of diastereomeric 2-(2′-deoxypent-1′-enopyranosyl)thiazole derivatives

AU - Kovács, L.

PY - 1995

Y1 - 1995

N2 - The supposed interplay of remote group participation and anomeric, allylic and stereodirecting effects exerted by different groups are invoked to explain the formation of a new stereocenter in unsaturated thiazole C-nucleosides 5 and 6.

AB - The supposed interplay of remote group participation and anomeric, allylic and stereodirecting effects exerted by different groups are invoked to explain the formation of a new stereocenter in unsaturated thiazole C-nucleosides 5 and 6.

KW - conformation

KW - remote group participation

KW - thiazole C-nucleoside

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VL - 132

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JO - Bulletin de la Societe Chimique de France

JF - Bulletin de la Societe Chimique de France

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