Thermodynamics of inclusion complex formation of β-cyclodextrin with a variety of surfactants differing in the nature of headgroup

Mária Benk, Z. Király

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

The inclusion complexation of β-cyclodextrin with various surfactants, possessing the same alkyl chain length but differing in the hydrophilic headgroup, was investigated by isothermal titration microcalorimetry. Sodium dodecyl sulfate, sodium dodecyl sulfonate, dodecyltrimethylammonium bromide and dodecyl(dimethyl)amine oxide were investigated. The major aim of this study was to elucidate the effects of temperature and the nature of the headgroup on the complex formation. Thermometric titrations were effected between the temperatures (288 and 348) K. The results provided the stoichiometry, the equilibrium constant and the reaction enthalpy of complexation. Changes in Gibbs energy, entropy and van't Hoff enthalpy were additionally calculated.

Original languageEnglish
Pages (from-to)211-216
Number of pages6
JournalJournal of Chemical Thermodynamics
Volume54
DOIs
Publication statusPublished - Nov 2012

Fingerprint

Cyclodextrins
Complexation
Titration
Surface-Active Agents
titration
Enthalpy
Surface active agents
enthalpy
surfactants
Thermodynamics
inclusions
thermodynamics
Equilibrium constants
Sodium dodecyl sulfate
Gibbs free energy
sulfonates
sodium sulfates
trucks
Chain length
Sodium Dodecyl Sulfate

Keywords

  • β-Cyclodextrin
  • Calorimetry
  • DTAB
  • Inclusion complexes
  • SDS
  • Surfactants

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Atomic and Molecular Physics, and Optics
  • Materials Science(all)

Cite this

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abstract = "The inclusion complexation of β-cyclodextrin with various surfactants, possessing the same alkyl chain length but differing in the hydrophilic headgroup, was investigated by isothermal titration microcalorimetry. Sodium dodecyl sulfate, sodium dodecyl sulfonate, dodecyltrimethylammonium bromide and dodecyl(dimethyl)amine oxide were investigated. The major aim of this study was to elucidate the effects of temperature and the nature of the headgroup on the complex formation. Thermometric titrations were effected between the temperatures (288 and 348) K. The results provided the stoichiometry, the equilibrium constant and the reaction enthalpy of complexation. Changes in Gibbs energy, entropy and van't Hoff enthalpy were additionally calculated.",
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AB - The inclusion complexation of β-cyclodextrin with various surfactants, possessing the same alkyl chain length but differing in the hydrophilic headgroup, was investigated by isothermal titration microcalorimetry. Sodium dodecyl sulfate, sodium dodecyl sulfonate, dodecyltrimethylammonium bromide and dodecyl(dimethyl)amine oxide were investigated. The major aim of this study was to elucidate the effects of temperature and the nature of the headgroup on the complex formation. Thermometric titrations were effected between the temperatures (288 and 348) K. The results provided the stoichiometry, the equilibrium constant and the reaction enthalpy of complexation. Changes in Gibbs energy, entropy and van't Hoff enthalpy were additionally calculated.

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