Thermodynamic driving force in the kinetic evaluation of thermoanalytical curves

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7 Citations (Scopus)

Abstract

This paper outlines the different ways of taking the distance from thermodynamic equilibrium into account in kinetic studies based on thermoanalytical experiments. The three main approaches are: (i) avoiding or neglecting the effect of the reverse reaction, (ii) describing the influence of distance from equilibrium on apparent kinetic parameters, and (iii) incorporating a driving force factor in the rate equation. Finally, the contradiction of the microscopic nature of the processes and the macroscopic character of the usual rate equation are briefly discussed.

Original languageEnglish
Pages (from-to)879-886
Number of pages8
JournalJournal of Thermal Analysis and Calorimetry
Volume60
Issue number3
DOIs
Publication statusPublished - Jan 1 2000

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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