Thermoanalytical study of O,O'-dibenzoyl-(2R,3R)-tartaric acid supramolecular compounds. Part II. Investigation of the resolution of racemic alcohols

Cs Kassai, R. Illés, G. Pokol, J. Sztatisz, E. Fogassy, D. Kozma

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7 Citations (Scopus)

Abstract

The resolution of three chiral alcohols with O,O'-dibenzoyl-(2R,3R)-tartaric acid (DBTA) via diastereoisomeric supramolecular compound formation was investigated with thermoanalytical methods. On the basis of TG measurements the DBTA:chiral alcohol molar ratio in the compounds is 1:1 which agrees with the results of single-crystal X-ray diffraction analysis. The DBTA - chiral alcohol supramolecular compounds have different supramolecular structure than the DBTA - achiral alcohol supramolecular compounds. The supramolecular compounds containing cyclohexanols have higher thermal stability than the compounds containing acyclic aliphatic alcohols. The amount of unreacted DBTA monohydrate in the solid phase can be determined both with DSC and with TG measurements.

Original languageEnglish
Pages (from-to)647-655
Number of pages9
JournalJournal of Thermal Analysis and Calorimetry
Volume62
Issue number3
DOIs
Publication statusPublished - Dec 1 2000

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ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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