Thermally Stimulated Discharge Current and Dynamic Mechanical Investigation of Polyisobutylene-Polybutylene Terephthalate Thermoplastic Multiblock Copolymers

Kálmán Marossy, G. Deák, S. Kéki, M. Zsuga

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8 Citations (Scopus)

Abstract

Characterization of polyisobutylene (PIB)-polybutylene terephthalate (PBT) multiblock copolymers by thermally stimulated discharge (TSD) current and dynamic mechanical analysis (DMA) methods is described. Both the length of the PIB segments (2200-10000 g/mol), and the overall composition (30-80 wt %) of the multiblock copolymers were varied. Both methods support the block structure of the multiblock copolymers investigated. Despite the apolar nature of the PIB segments, they proved to be detectable by the TSD method. The relaxation times and the mobility of the chain length were also determined.

Original languageEnglish
Pages (from-to)814-818
Number of pages5
JournalMacromolecules
Volume32
Issue number3
Publication statusPublished - Feb 9 1999

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Thermoplastics
Copolymers
Dynamic mechanical analysis
Chain length
Relaxation time
Chemical analysis
polyisobutylene
poly(1,4-butylene terephthalate)

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

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abstract = "Characterization of polyisobutylene (PIB)-polybutylene terephthalate (PBT) multiblock copolymers by thermally stimulated discharge (TSD) current and dynamic mechanical analysis (DMA) methods is described. Both the length of the PIB segments (2200-10000 g/mol), and the overall composition (30-80 wt {\%}) of the multiblock copolymers were varied. Both methods support the block structure of the multiblock copolymers investigated. Despite the apolar nature of the PIB segments, they proved to be detectable by the TSD method. The relaxation times and the mobility of the chain length were also determined.",
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T1 - Thermally Stimulated Discharge Current and Dynamic Mechanical Investigation of Polyisobutylene-Polybutylene Terephthalate Thermoplastic Multiblock Copolymers

AU - Marossy, Kálmán

AU - Deák, G.

AU - Kéki, S.

AU - Zsuga, M.

PY - 1999/2/9

Y1 - 1999/2/9

N2 - Characterization of polyisobutylene (PIB)-polybutylene terephthalate (PBT) multiblock copolymers by thermally stimulated discharge (TSD) current and dynamic mechanical analysis (DMA) methods is described. Both the length of the PIB segments (2200-10000 g/mol), and the overall composition (30-80 wt %) of the multiblock copolymers were varied. Both methods support the block structure of the multiblock copolymers investigated. Despite the apolar nature of the PIB segments, they proved to be detectable by the TSD method. The relaxation times and the mobility of the chain length were also determined.

AB - Characterization of polyisobutylene (PIB)-polybutylene terephthalate (PBT) multiblock copolymers by thermally stimulated discharge (TSD) current and dynamic mechanical analysis (DMA) methods is described. Both the length of the PIB segments (2200-10000 g/mol), and the overall composition (30-80 wt %) of the multiblock copolymers were varied. Both methods support the block structure of the multiblock copolymers investigated. Despite the apolar nature of the PIB segments, they proved to be detectable by the TSD method. The relaxation times and the mobility of the chain length were also determined.

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VL - 32

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