Thermal Stability of the CH3 Group Adsorbed on the Pd(100) Surface

Frigyes Solymosi, Karoly Révész

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65 Citations (Scopus)

Abstract

The adsorption and subsequent dissociation of CH3I on Pd(100) have been investigated with ultraviolet photoelectron spectroscopy, Auger electron spectroscopy, temperature-programmed desorption, and work function change over the temperature range 85–600 K. We find that CH3I adsorbs molecularly at 85 K and dissociates at 100–150 K to give adsorbed I and CH3. The latter compound decomposes above 150 K to yield methane. The thermal stability of adsorbed CH3 (250 K) is much lower than that found for CH3 (400 K) formed in the dissociation of CH3OH on the Pd(111) surface2.

Original languageEnglish
Pages (from-to)9145-9147
Number of pages3
JournalJournal of the American Chemical Society
Volume113
Issue number24
DOIs
Publication statusPublished - Nov 1 1991

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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