Thermal decomposition of polyamide-6 in the presence of PVC

Ferenc Kubatovics, Marianne Blazsó

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Besides the monomer some minor but characteristic volatile thermal decomposition products are observed pyrolysing polyamide-6 in the presence of PVC. It was proven that hydrogen chloride thermally eliminated from PVC gives rise to facilitated depolymerization of PA-6, partial hydrolysis of the amide groups, evolution of 6-chlorohexanenitrile, and promoted nitrile and vinyl end group formation. A mechanism is proposed for the advance of these reactions by hydrogen chloride. Depolymerization and hydrolysis are initiated at a considerably lower temperature in the presence of PVC, at the temperature of the hydrogen chloride elimination from the latter. Studying the aspect of high temperature decomposition it was observed that the presence of PVC severely increased the hydrogen cyanide evolution from PA-6 at 900°C.

Original languageEnglish
Pages (from-to)349-354
Number of pages6
JournalMacromolecular Chemistry and Physics
Volume201
Issue number3
DOIs
Publication statusPublished - Feb 2000

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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