Thermal decomposition of hydrotalcite with hexacyanoferrate(II) and hexacyanoferrate(III) anions in the interlayer: A controlled rate thermal analysis study

Sara J. Palmer, J. Kristóf, Veronika Vágvölgyi, Erzsébet Horváth, R. L. Frost

Research output: Contribution to journalArticle

3 Citations (Scopus)

Abstract

The mechanism for the decomposition of hydrotalcite remains unsolved. Controlled rate thermal analysis enables this decomposition pathway to be explored. The thermal decomposition of hydrotalcites with hexacyanoferrate(II) and hexacyanoferrate(III) in the interlayer has been studied using controlled rate thermal analysis technology. X-ray diffraction shows the hydrotalcites have a d(003) spacing of 10.9 and 11.1 Å which compares with a d-spacing of 7.9 and 7.98 Å for the hydrotalcite with carbonate or sulphate in the interlayer. Calculations show dehydration with a total loss of 7 moles of water proving the formula of hexacyanoferrate(II) intercalated hydrotalcite is Mg 6Al2(OH)16[Fe(CN)6] 0.5•7H2O and 9.0 moles for the hexacyanoferrate(III) intercalated hydrotalcite with the formula of Mg6Al 2(OH)16[Fe(CN)6]0.66•9H 2O. CRTA technology indicates the partial collapse of the dehydrated mineral. Dehydroxylation combined with CN unit loss occurs in two isothermal stages at 377 and 390°C for the hexacyanoferrate(III) and in a single isothermal process at 374°C for the hexacyanoferrate(III) hydrotalcite.

Original languageEnglish
Pages (from-to)449-454
Number of pages6
JournalJournal of Thermal Analysis and Calorimetry
Volume96
Issue number2
DOIs
Publication statusPublished - May 1 2009

Keywords

  • Controlled rate thermal analysis CRTA)
  • Hexacyanoferrate(II)
  • Hexacyanoferrate(III)
  • Hydrotalcite

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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