Thermal behaviour of transition metal-containing zirconium phosphate

L. Szirtes, A. M. Szeleczky, A. O. Rajeh, E. Kuzmann

Research output: Contribution to journalConference article

4 Citations (Scopus)

Abstract

The thermal behaviour of Co(II), Ni(II) and Zn(II)-containing zirconium phosphate of α type was investigated. XRPD analysis revealed that, for the samples containing Co(II) or Ni(II), the first reflection of the solid phase is split into a doublet. In contrast, when Zn(II) is present, a single solid phase system is formed. The thermal behaviour of the materials followed this sequence. For the samples containing Co(II) or Ni(II), phase-transition processes were found and there was also a loss of crystal water, but for the sample containing Zn(II) there was only one endothermic effect, which corresponded to the decomposition of phosphate groups.

Original languageEnglish
Pages (from-to)447-451
Number of pages5
JournalJournal of Thermal Analysis and Calorimetry
Volume56
Issue number1
Publication statusPublished - Jan 1 1999
EventProceedings of the 1998 7th European Symposium on Thermal Analysis and Calorimetry - Balatonfured, Hung
Duration: Aug 30 1998Sep 4 1998

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry

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